An essential oil is a concentrated, hydrophobic liquid containing volatile aromatic compounds from plants. It is produced by distillation. Other extraction processes to obtain aromatic plant compounds include expression, or solvent extraction. Essential oils are used in perfumery, aromatherapy, cosmetics, incense, for flavoring food and drink, and to a lesser extent, in medicine and household cleaning products. They are valuable commodities to the fragrance and flavorant industries.
Essential oil is also known as volatile oil and ethereal oil. It may also be referred to as "oil of" the raw plant material from which it was extracted, such as oil of clove. The term essential is intended to indicate that the oil is the fragrant essence of the plant from which it is extracted and not in the more common grammatical sense of being indispensable. It is not to be confused with essential fatty acids.
The medical use of vegetable oils has a long and distinguished history. Many oils that are used medicinally are essential oils, which are distilled rather than pressed or otherwise extracted. Medical properties claimed by those who sell medicinal oils vary from skin treatments to remedies for cancer, and are often based on historical use of these oils for these purposes. Such claims are now subject to regulation in most countries, and have grown correspondingly more vague, to stay within these regulations.

Interest in such uses of essential oils has enjoyed a revival in recent decades, with the popularity of aromatherapy, in which oils are heated and volatilized.
DistillationToday, most common essential oils, such as lavender, peppermint, and eucalyptus, are distilled. Raw plant material, consisting of the flowers, leaves, wood, bark, roots, seeds, or peel, is put into an alembic (distillation apparatus) over water, As the water is heated the steam passes through the plant material, vaporizing the volatile compounds. The vapors flow through a coil where they condense back to liquid, which is then collected in the receiving vessel.
Most oils are distilled in a single process. One exception is Ylang-ylang (Cananga odorata), which takes 22 hours to complete through a Fractional distillation.
The water recondensed from the distillation process is referred to as a hydrosol, hydrolat, herbal distillate or plant water essence, which may be sold as another fragrant product. Popular hydrosols are rose water, lavender water, lemon balm, clary sage and orange blossom water. The use of herbal distillates in cosmetics is increasing. Some plant hydrosols have unpleasant smells and are therefore not sold.
ExpressionMost citrus peel oils are usually expressed mechanically, or cold-pressed. Due to the large quantities of oil in citrus peel and the relatively low cost to grow and harvest the raw materials, citrus-fruit oils are cheaper than most other essential oils. Lemon or sweet orange oils that are obtained as by-products of the commercial citrus industry are even cheaper.
Prior to the discovery of distillation, essential oils (EO) were extracted by pressing.
Solvent extractionMost flowers contain very little volatile oil to undergo expression and their chemical components are too delicate and easily denatured by the high heat used in steam distillation. Instead, a solvent such as hexane or supercritical carbon dioxide is used to extract the oils. Extracts from hexane and other hydrophobic solvent are called concretes, which is mixture of essential oil, waxes, resins, and other lipophilic (oil soluble) plant material.
Although highly fragrant, concretes contain large quantities of non-fragrant waxes and resins. As such another solvent, often ethyl alcohol, which only dissolves the fragrant low-molecular weight compounds, is used to extract the fragrant oil from the concrete. The alcohol is removed by a second distillation, leaving behind the absolute.
Supercritical carbon dioxide is used as a solvent in supercritical fluid extraction. This method has many benefits, including avoiding petrochemical residues in the product. It does not yield an absolute directly. The supercritical carbon dioxide will extract both the waxes and the essential oils that make up the concrete. Subsequent processing with liquid carbon dioxide, achieved in the same extractor by merely lowering the extraction temperature, will separate the waxes from the essential oils. This lower temperature process prevents the decomposition and denaturing of compounds and provides for a superior product. When the extraction is complete, the pressure is reduced to ambient and the carbon dioxide reverts back to a gas, leaving no residue. Although supercritical carbon dioxide is also used for making decaffeinated coffee, the actual process is different.
Labels: Essential oils, Supercritical